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Synthesis and Electrochemical Properties of Novel 1,3,5‐Tris(oligothienyl)benzenes: A New Generation of 3D Reticulating Agents
Author(s) -
Cherioux F.,
Guyard L.
Publication year - 2001
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/1616-3028(200108)11:4<305::aid-adfm305>3.0.co;2-y
Subject(s) - materials science , electrochemistry , tris , nanotechnology , combinatorial chemistry , chemical engineering , chemistry , electrode , biochemistry , engineering
Novel 1,3,5‐tris(oligothienyl)benzenes have been synthesized by an efficient and very easy trimerization reaction and their optimized three‐dimensional geometry has been determined by semiempirical computations. Their electrochemical behavior has been investigated; their electropolymerization with 2,2′‐bithiophene led to the development of two‐ or three‐dimensional conducting polymers.