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Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts
Author(s) -
De bruyn Mario,
De Vos Dirk E.,
Jacobs Pierre A.
Publication year - 2002
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(200212)344:10<1120::aid-adsc1120>3.0.co;2-4
Subject(s) - chemistry , allylic rearrangement , catalysis , reduction (mathematics) , transfer hydrogenation , hydrogen , chemoselectivity , organic chemistry , ketone , combinatorial chemistry , ruthenium , geometry , mathematics
α,β‐Unsaturated ketones were reduced to allylic alcohols with high chemo‐ and diastereoselectivity, using Zr and Hf compounds heterogenised on mesoporous molecular sieves.