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Asymmetric Organocatalytic Diels–Alder Reactions on Solid Support
Author(s) -
Selkälä Sami A.,
Tois Jan,
Pihko Petri M.,
Koskinen Ari M. P.
Publication year - 2002
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(200210)344:9<941::aid-adsc941>3.0.co;2-m
Subject(s) - chemistry , enantioselective synthesis , organocatalysis , catalysis , reagent , reactivity (psychology) , diels–alder reaction , organic chemistry , combinatorial chemistry , medicine , alternative medicine , pathology
Asymmetric organocatalysis on solid support combines the environmental advantages of metal‐free catalysts and the ease of operation of solid‐supported reagents. Enantioselective organocatalytic DielsAlder reactions have been demonstrated by two different solid‐supported chiral organocatalysts. The catalysts are easy to recover and they can be reused. The reactivity of the catalyst can be tuned by changing the solid support.