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Catalyzed Reactions of Enolates and Cations: A Novel Method for Enolate Alkylation
Author(s) -
Gansäuer Andreas,
Fielenbach Doris,
Stock Christoph
Publication year - 2002
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(200209)344:8<845::aid-adsc845>3.0.co;2-5
Subject(s) - chemistry , alkylation , catalysis , aldehyde , solvent , organic chemistry , medicinal chemistry
Abstract The first tertiary alkylations, alkoxyalkylations, and aldehyde enolate allylations are described proceeding with low catalyst loading (0.1 mol % to 5 mol %). The reactions proceed in short times, can be performed without solvent and under ambient conditions.