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Ruthenium‐Catalyzed Olefin Cross Metathesis of Styrenes as an Alternative to the Heck and Cross‐Coupling Reactions
Author(s) -
Chatterjee Arnab K.,
Toste F. Dean,
Choi TaeLim,
Grubbs Robert H.
Publication year - 2002
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(200208)344:6/7<634::aid-adsc634>3.0.co;2-k
Subject(s) - chemistry , heck reaction , allylic rearrangement , olefin fiber , catalysis , ruthenium , olefin metathesis , organic chemistry , metathesis , coupling reaction , salt metathesis reaction , alkene , palladium , polymerization , polymer
The use of olefin cross metathesis as a method for the formation of styrenyl‐olefins is described using allylic substituted olefins and electron‐deficient olefins. These methods provide an orthogonal method to alternative olefination strategies, such as the Heck reaction. These methods have also been employed in the total synthesis of 3‐flavanols.