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Amphiphilic Resin‐Supported Rhodium‐Phosphine Catalysts for C‐C Bond Forming Reactions in Water
Author(s) -
Uozumi Yasuhiro,
Nakazono Maki
Publication year - 2002
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(200206)344:3/4<274::aid-adsc274>3.0.co;2-s
Subject(s) - rhodium , chemistry , hydroformylation , phosphine , catalysis , amphiphile , ethylene glycol , polymer chemistry , organic chemistry , benzene , polystyrene , polymer , copolymer
Amphiphilic resin‐supported rhodium‐phosphine complexes were prepared on polystyrene‐poly(ethylene glycol) graft co‐polymer (1% DVB cross‐linked) beads. The immobilized rhodium complexes exhibited high catalytic activity in water to promote hydroformylation of 1‐alkenes, [2+2+2] cyclotrimerization of internal alkynes forming benzene rings, and 1,4‐addition of arylboronic acids.