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An Efficient Synthesis of Ring‐Opening Metathesis Monomers and Polymers Containing Carbazole and Other Electron‐Rich Moieties
Author(s) -
Gao Daxin,
Roh Yeonsuk,
Bauld Nathan Louis
Publication year - 2001
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(20010330)343:3<269::aid-adsc269>3.0.co;2-9
Subject(s) - chemistry , norbornene , carbazole , monomer , cycloaddition , metathesis , polymer chemistry , ring opening metathesis polymerisation , ring (chemistry) , polymer , romp , organic chemistry , polymerization , catalysis
An efficient synthesis of ring‐opening metathesis monomers and polymers containing ionizable moieties such as N ‐carbazolyl, 2‐dibenzofuranyl, 2‐dibenzothiophenyl, and 4‐anisyl functionalities has been developed, using cation radical Diels‐Alder cycloaddition chemistry to generate the appropriate norbornene‐type monomers.