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Palladium(II)‐Catalyzed Oxidation of Alcohols with Air as Reoxidant
Author(s) -
Hallman Kristina,
Moberg Christina
Publication year - 2001
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/1615-4169(20010330)343:3<260::aid-adsc260>3.0.co;2-8
Subject(s) - palladium , chemistry , catalysis , alcohol oxidation , organic chemistry , primary (astronomy) , tertiary alcohols , physics , astronomy
Oxidation of primary and secondary aliphatic and secondary benzylic alcohols into their corresponding aldehydes and ketones was achieved in good yields with palladium catalysts using air as the reoxidant of palladium. The use of palladacycle 1 resulted in higher yields and a faster reaction than the use of Pd(OAc) 2 as the palladium source.