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Indole and Quinoline Synthesis via Intramolecular Pauson‐Khand Reactions of Enamines and Allylamines
Author(s) -
Domínguez Gema,
Casarrubios Luis,
RodríguezNoriega Javier,
PérezCastells Javier
Publication year - 2002
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/1522-2675(200209)85:9<2856::aid-hlca2856>3.0.co;2-5
Subject(s) - chemistry , sonogashira coupling , indole test , combinatorial chemistry , organic chemistry , stereochemistry , palladium , catalysis
Syntheses of indoles and quinolines based upon the Pauson‐Khand reaction is described. The starting materials are an aromatic ethynylenamine and ethynylallylamine, which are obtained via Sonogashira coupling. Also, an aromatic ynamine is used for an attempt to synthesize indole.