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Chemistry of N ‐Hydroxyguanidines: Photo‐Sensitized Oxygenation and Reaction with Nitric Oxide
Author(s) -
Kabasawa Hiroyo,
Ikeno Masako,
Suzukawa Masahiro,
Higuchi Keiro,
Yanagisawa Keiko,
Seki Hiroko,
Tokunaga Tatsuhiro,
Ishikawa Tsutomu
Publication year - 2002
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/1522-2675(200209)85:9<2636::aid-hlca2636>3.0.co;2-l
Subject(s) - chemistry , nitrosation , derivative (finance) , urea , nitric oxide , medicinal chemistry , organic chemistry , financial economics , economics
The chemistry of N ‐hydroxyguanidines, focusing on photo‐sensitized oxygenation and reaction with nitric oxide (NO), was examined. In the former reaction, a urea derivative was obtained as the main product together with the generation of NO. On the other hand, in the latter case, oxidative nitrosation occurred under aerobic conditions to give a nitrosourea derivative, which was also obtained from urea by the same treatment.