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Synthesis of a New System Containing a Pyramidalized Double Bond: Lack of Reactivity of a Strongly Protected Pyramidalized Double Bond
Author(s) -
Saraçogˇlu Nurullah,
Balci Metin
Publication year - 2001
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/1522-2675(20010321)84:3<707::aid-hlca707>3.0.co;2-p
Subject(s) - chemistry , double bond , reactivity (psychology) , inert , chemical bond , stereochemistry , photochemistry , organic chemistry , pathology , medicine , alternative medicine
The chemical reactivity of syn ‐ 3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemical reactions. To determine the reactivity of this central double bond, we synthesized syn ‐ and anti ‐ 7 and recorded their photoelectron spectra. Low first‐ionization potentials of syn ‐ and anti ‐ 7 (7.6 eV) clearly indicated that these compounds should be highly reactive.