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Layer‐by‐Layer Grafting of Molecularly Imprinted Polymers via Iniferter Modified Supports
Author(s) -
Sellergren B.,
Rückert B.,
Hall A.J.
Publication year - 2002
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/1521-4095(20020903)14:17<1204::aid-adma1204>3.0.co;2-o
Subject(s) - materials science , grafting , molecularly imprinted polymer , polymer , chemical engineering , layer (electronics) , template , molecular imprinting , polymer chemistry , nanotechnology , organic chemistry , composite material , catalysis , selectivity , chemistry , engineering
“Living” functional composite materials have been prepared by grafting of molecularly imprinted polymers (MIPs) from dithiocarbamate‐modified porous silica supports (see Figure). The living properties of the system are demonstrated by consecutive grafting of two polymer layers imprinted with chiral templates. The enantioselectivity of the first layer is reversed by grafting a second layer imprinted with the antipode.