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A Cross‐linked Large Channel Organic Coordination Solid
Author(s) -
Xu Z.,
Lee S.,
Kiang Y.H.,
Mallik A. B.,
Tsomaia N.,
Mueller K. T.
Publication year - 2001
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/1521-4095(200105)13:9<637::aid-adma637>3.0.co;2-s
Subject(s) - trifluoromethanesulfonate , mesoscopic physics , materials science , covalent bond , molecule , polymer , salt (chemistry) , silylation , nanotechnology , metal , organic molecules , organic chemistry , metallurgy , catalysis , chemistry , composite material , physics , quantum mechanics
A new approach to fully covalent crystalline networks is revealed. It is a template technique in which a metal salt is co‐crystallized with a mesoscopic organic molecule. The Figure shows a phenylacetylenenitrile silver triflate molecule, which is reacted with silyl ditriflates to form high molecular weight polymers. Details of the technique and physical properties are discussed.