Premium
Fast Magic‐Angle Spinning and Double‐Quantum 1 H Solid‐State NMR Spectroscopy of Polyelectrolyte Multilayers
Author(s) -
Rodriguez L. N. J.,
De Paul S. M.,
Barrett C. J.,
Reven L.,
Spiess H. W.
Publication year - 2000
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/1521-4095(200012)12:24<1934::aid-adma1934>3.0.co;2-s
Subject(s) - polyelectrolyte , magic angle spinning , materials science , spinning , solid state nuclear magnetic resonance , colloid , magic angle , spectroscopy , nmr spectra database , spectral line , nuclear magnetic resonance spectroscopy , solid state , chemical engineering , chemistry , polymer chemistry , nuclear magnetic resonance , polymer , composite material , physics , quantum mechanics , engineering , astronomy
Polyelectrolyte multilayers on silica colloids are investigated here using a combination of fast magic‐angle spinning (MAS) and double‐quantum (DQ) solid‐state 1 H NMR techniques. 2D DQ 1 H NMR spectra of the bulk complex and the multilayer films (see Figure) are found to be similar, revealing complexation between the alternating layers of poly(sodium 4‐styrenesulfonate) (PSS) and poly(diallyldimethylammonium chloride) (PDADMAC).