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Ignition Characteristics of Zr/BaCrO 4 Pyrolant
Author(s) -
Kuwahara Takuo,
Tohara Chiharu
Publication year - 2002
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/1521-4087(200211)27:5<284::aid-prep284>3.0.co;2-t
Subject(s) - ignition system , zirconium , materials science , minimum ignition energy , barium , chromate conversion coating , analytical chemistry (journal) , metallurgy , thermodynamics , chemistry , chromatography , chromium , physics
Zirconium (Zr) and barium chromate (BaCrO 4 ) is a pyrolant of high energy content. Zr has a high and BaCrO 4 a low sensitivity. The mixture of the two components has been investigated with respect to its ignition characteristics. The ignition delay time of the pyrolant decreases with an increasing concentration of Zr particles. That means, since the concentration of Zr is proportional to its total surface area S , the ignition delay time decreases with increasing S. An ignition delay time, τ ig , is obtained adding τ p and τ c , where τ p is the physical ignition delay time and τ c is the chemical ignition delay time. τ p does not change when the concentration of Zr increases. However, τ c decreases with an increasing concentration of Zr, resulting in an increase of its surface area S. It is expected that Zr easily reacts with barium chromate.