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Mass Spectra of Unlabeled and Isotopically Labeled Hexamethylene Triperoxide Diamine (HMTD)
Author(s) -
Oxley Jimmie,
Zhang Jun,
Smith James,
Cioffi Eugene
Publication year - 2000
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/1521-4087(200012)25:6<284::aid-prep284>3.0.co;2-x
Subject(s) - diamine , chemistry , mass spectrum , fragmentation (computing) , mass spectrometry , medicinal chemistry , polymer chemistry , chromatography , computer science , operating system
Electron impact (EI) mass spectra of unlabeled and 13 C/ 15 N labeled hexamethylene triperoxide diamine were obtained using a direct insertion probe. The most prominent peaks were the molecular ions ( m/z 208 and m/z 216, respectively). An EI fragmentation pathway is proposed based on the mass spectral evidence.