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The Strontium Complex Nitrates of Carbohydrazide as a Non‐Azide Gas Generator for Safer Driving–the Thermal Behavior of the Sr Complex with Various Oxidizing Agents
Author(s) -
Akiyoshi Miyako,
Nakamura Hidetsugu,
Hara Yasutake
Publication year - 2000
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/1521-4087(200011)25:5<224::aid-prep224>3.0.co;2-o
Subject(s) - oxidizing agent , carbohydrazide , chemistry , stoichiometry , strontium , halogen , azide , hum , inorganic chemistry , organic chemistry , alkyl , art , performance art , art history
As a new azide‐free gas generant, the thermal behavior of the Sr complex nitrate of carbohydrazide was investigated in the mixed system with various oxidizing agents (KClO 4 , KBrO 3 , Sr(NO 3 ) 2 , KNO 3 ). For the differential thermal analysis, the initial temperature of the reaction of mixtures with KBrO 3 was lower than that of the pure complex, and the reaction was very vigorous. The reactions with oxidizing agents except for KBrO 3 were thought to proceed moderately. The heat of combustion at the stoichiometric composition increased according to the tendency of the calculated theoretical value based on the chemical stoichiometric equation. The burning rate of the KBrO 3 system was very high compared with the other mixed systems, and was controlled by the rate of reaction. The pressure dependence was high in the case of using the nitrate as an oxidizing agent. In all the systems, N 2 and CO 2 gases account for 99% of all the evolved gases during the combustion. In the case of using an oxidizing agent containing a halogen, the halogen ion was only slightly detected during the combustion.