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Synthesis, Structure and Characterizations of a Molybdenum Sulfide Complex with inorganic Cluster [Mo 3 S 13 ] 2‐ and Organic Amine Me 4 N +
Author(s) -
Lu S.,
Ke Y.,
Li J.,
Zhang Y.
Publication year - 2002
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/1521-4079(200211)37:11<1153::aid-crat1153>3.0.co;2-4
Subject(s) - chemistry , crystal structure , crystallography , amine gas treating , cluster (spacecraft) , molybdenum , sulfide , molybdenum disulfide , trigonal crystal system , sulfur , hydrothermal synthesis , ion , single crystal , hydrothermal circulation , molecule , inorganic chemistry , materials science , organic chemistry , chemical engineering , computer science , metallurgy , programming language , engineering
The complex of (Me 4 N) 2 Mo 3 S 13 ( I ) has been synthesized under mild hydrothermal condition. The crystal structure was determined by single crystal X‐ray diffraction at room temperature. Crystal data: M = 854.91, Trigonal, space group P 3 (No. 143), a = 11.2351(8) Å, c = 5.8885(6) Å, and Z = 1, There is an inorganic [Mo 3 S 13 ] 2‐ core composed of a Mo 3 ‐triangle, a μ 3 ‐S atom, three doubly bridging disulfide and three terminal disulfide. Two organic amine ions act as the positive charge to balance the [Mo 3 S 13 ] 2‐ cluster.