Premium
The Crystal Structure of the Cluster Complex [{Co(phen) 2 } 2 V 4 O 12 ] · H 2 O
Author(s) -
Kucsera R.,
Gyepes R.,
Žúrková L.
Publication year - 2002
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/1521-4079(200208)37:8<890::aid-crat890>3.0.co;2-2
Subject(s) - bimetallic strip , crystallography , crystal structure , stacking , chemistry , denticity , cluster (spacecraft) , group (periodic table) , ion , ligand (biochemistry) , stereochemistry , metal , receptor , organic chemistry , programming language , biochemistry , computer science
The crystal structure of [{Co(phen) 2 } 2 V 4 O 12 ] · H 2 O consists of hexanuclear bimetallic clusters [{Co(phen) 2 } 2 V 4 O 12 ]. The cyclic [V 4 O 12 ] 4‐ anion acts as a bidentate bridging ligand between the two [Co(phen) 2 ] 2+ cations. The π‐π stacking interactions between the parallel 1,10‐phenantroline (phen) groups play a significant role in stabilizing this structure. The title compound crystallizes in the P2 1 /c space group.