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Crystal Structure of the Amine‐Carbonato‐Cobalt(III) Complex [Co(CO3)(L 1 )]ClO4 with Aminoalkyl Pendant‐Arm [12]eneN4, L 1 = 9‐(3‐aminopropyl)‐1,5,9‐Triazacyclododecene
Author(s) -
Massoud S.S.,
Mautner F.A.,
AbuYoussef M.A.M.
Publication year - 2000
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/1521-4079(200010)35:10<1229::aid-crat1229>3.0.co;2-f
Subject(s) - monoclinic crystal system , octahedron , crystal structure , crystallography , chemistry , cobalt , amine gas treating , group (periodic table) , crystal (programming language) , stereochemistry , inorganic chemistry , organic chemistry , computer science , programming language
The crystal and molecular structure of the title complex [Co(CO3)(L1)]ClO4 was determined from X‐ray diffraction data using direct methods. The crystals are monoclinic, a = 13.588(4) Å, b = 9.049(3) Å, c = 15.569(6) Å, β = 114.75(2)°, Z = 4, V = 1738.5(10) Å 3 , space group P21/n. The structure consists of isolated [Co(CO3)(C12H26N4)]+ complex cations, with distorted octahedral geometry and ClO4‐ counter anions. The results are discussed in relation to similar macrocycle and carbonato analogues.