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35 Cl Nuclear Magnetic Resonance Study in Bis(4‐Chlorophenyl)Sulphone [(ClC 6 H 4 ) 2 SO 2 ]
Author(s) -
Taye A.,
Michel D.
Publication year - 2002
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/1521-3951(200210)233:3<519::aid-pssb519>3.0.co;2-b
Subject(s) - quadrupole , nuclear quadrupole resonance , principal axis theorem , spins , nuclear magnetic resonance , tensor (intrinsic definition) , nuclear magnetic resonance spectroscopy , chemistry , asymmetry , resonance (particle physics) , nmr spectra database , spectral line , condensed matter physics , physics , atomic physics , mathematics , quantum mechanics , geometry , pure mathematics
35 Cl NMR measurements of the central transitions (—1/2 ↔ +1/2) on a multidomain crystal of bis(4‐chlorophenyl)sulphone (BCPS) were performed at room temperature. The quadrupole tensors and the temperature dependence of the 35 Cl NMR resonance frequencies have been analysed. Since the Larmor frequency ν L is of comparable size with the quadrupole frequency ν Q an exact solution of the problem of the eigenvalues for a system of spins with I = 3/2 in presence of an external magnetic field was necessary in order to evaluate the principal values, the directions of the principal axes, and the asymmetry parameter η of the quadrupole coupling tensor from the angular dependent NMR spectra. The conclusions from the NMR measurements are in very good agreement with the results of the 35 Cl nuclear quadrupole resonance (NQR) and the X‐ray diffraction (XRD) studies on BCPS.