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Ester‐type banana‐shaped monomers and investigations of their electro‐optical properties
Author(s) -
FodorCsorba Katalin,
Vajda Aniko,
Galli Giancarlo,
Jákli Antal,
Demus Dietrich,
Holly Sándor,
GácsBaitz Eszter
Publication year - 2002
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/1521-3935(200207)203:10/11<1556::aid-macp1556>3.0.co;2-l
Subject(s) - monomer , polymer chemistry , polymer science , type (biology) , materials science , chemistry , composite material , polymer , geology , paleontology
New banana‐shaped monomers 1a–1f , based on the 1,3‐phenylene bis{4‐[4′‐(alkenyloxy)benzoyloxy]}benzoate bent structure were prepared. The central 1,3‐phenylene ring was either unsubstituted ( 1a , 1b ) or had a 2‐methyl substituent ( 1c , 1d ) or a 4‐chloro substituent ( 1e , 1f ), respectively. The occurrence of mesophases greatly depended on the chemical structure of the banana‐shaped molecules. Whilst 1,3‐phenylene bis{4‐[4′‐(10‐undecenyloxy)benzoyloxy]}benzoate ( 1b , acronym Pbis11BB) formed a monotropic B 2 phase, the 4‐chloro derivatives showed conventional nematic and SmC phases. In contrast, the 2‐methyl derivatives did not form any kind of mesophases. MOPAC/AM1 semi‐empirical calculations allowed evaluation of the value and orientation of the electric dipole vectors and of the twist angles of the central phenyl ring with respect to the outer rings. Electro‐optical investigations showed that the B 2 phase of 1b was antiferroelectric with a 45° tilt angle between 91–75 °C ( P = 320 nC · cm −2 ) and a switching time in the range of 50 μs in a E = 15 V · μm −1 field.Synthetic route for the preparation of monomers 1a–1f .