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Swelling and Mechanical Properties of Solution‐Crosslinked Poly(isobutylene) Gels
Author(s) -
Durmaz Selda,
Fank Sinan,
Okay Oguz
Publication year - 2002
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/1521-3935(20020301)203:4<663::aid-macp663>3.0.co;2-w
Subject(s) - swelling , isobutylene , polymer chemistry , vulcanization , cyclohexane , natural rubber , solvent , polymer , toluene , materials science , chemical engineering , rubber elasticity , chemistry , butyl rubber , composite material , copolymer , organic chemistry , engineering
We prepared several series of poly(isobutylene) (PIB) gels starting from butyl rubber in dilute toluene solutions using sulfur monochloride as a crosslinking agent. Solution and suspension‐crosslinking techniques were used for the preparation of PIB gels in the form of rods, membranes, and beads in the size range of 1 to 3 mm. The gels were subjected to dynamic and equilibrium swelling measurements in toluene and cyclohexane as well as to the elasticity tests. Depending on the amounts of sulfur monochloride and butyl rubber in the crosslinking solution, PIB gels with different swelling capacities and elastic moduli were synthesized. The swelling ratio of the gels first increased rapidly with increasing swelling time but then decreased until an equilibrium was obtained. This unusual swelling behavior was accompanied with an increase of the elastic moduli of the gels during the swelling process. The results were explained with the post‐crosslinking reactions taking place during the swelling process of PIB gels. By using the theory of equilibrium swelling, the number of segments in the network chains and the polymer‐solvent interaction parameters were calculated for PIB gels prepared under various reaction conditions.