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The Swelling Behavior of Polyelectrolyte Multilayers in Air of Different Relative Humidity and in Water
Author(s) -
Kügler Ralf,
Schmitt Johannes,
Knoll Wolfgang
Publication year - 2002
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/1521-3935(20020101)203:2<413::aid-macp413>3.0.co;2-r
Subject(s) - swelling , polyelectrolyte , relative humidity , polymer chemistry , humidity , chemical engineering , materials science , polymer science , chemistry , composite material , polymer , thermodynamics , physics , engineering
The swelling properties of physisorbed polyelectrolyte multilayer self‐assemblies with alternating polyion charge in humid air and in aqueous environment were investigated via X‐ray and neutron reflectometry as well as optically, using surface plasmon spectroscopy. The sorption behavior was similar to that found for neutral polymers and was related to an internal screening of the charges of the adjacent layers owing to the high entanglement of the polyelectrolyte chains and the resulting low mobility of the polymer segments. The screening was found to be incomplete only in the top layer, resulting in a net charged surface.