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Radiation Synthesis of Linear and Crosslinked Poly[2‐(methacryloyloxy)ethyl]trimethylammonium Chloride and Complex Formation with Potassium Hexacyanoferrates (II, III) in Aqueous Solutions
Author(s) -
Khutoryanskiy Vitaliy V.,
Kujawa Piotr,
Nurkeeva Zauresh S.,
Rosiak Janusz M.
Publication year - 2001
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/1521-3935(20010401)202:7<1089::aid-macp1089>3.0.co;2-s
Subject(s) - chemistry , aqueous solution , chloride , polymer chemistry , stoichiometry , polymerization , ionic strength , potassium , ionic bonding , inorganic chemistry , polymer , ion , organic chemistry
Linear and crosslinked poly[2‐(methacryloyloxy)ethyl]trimethylammonium chloride was synthesized by γ ‐irradiation polymerization in aqueous solutions. Interactions between linear poly[2‐(methacryloyloxy) ethyl]trimethylammonium chloride and low molecular coordination compounds K 3 [Fe(CN) 6 ] and K 4 [Fe(CN) 6 ] have been studied in aqueous solutions by viscometric and turbidimetric measurements. The formation of complexes with certain stoichiometry depending on the nature of the low molecular ion was detected. Hydrogels of poly[2‐(methacryloyloxy)ethyl]trimethylammonium chloride absorb these salts and undergo contraction. The stability of the complexes formed in different ionic strength media has been evaluated.