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Preparation and Characterization of Novel UV‐Curable Urethane Methacrylate Difunctional Monomers and Their Structure‐Property Relationships, 1
Author(s) -
İnan Tülay Yılmaz,
Ekinci Ekrem,
Yıldız Emel,
Kuyulu Abdülkadir,
Güngör Attila
Publication year - 2001
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/1521-3935(20010201)202:4<532::aid-macp532>3.0.co;2-i
Subject(s) - methacrylate , alkoxy group , polymer chemistry , monomer , thermal stability , methyl methacrylate , ethylene glycol , materials science , thermogravimetric analysis , ultimate tensile strength , chemistry , polymer , organic chemistry , composite material , alkyl
Four new UV‐curable cross‐linking agents namely 2,2‐bis(4‐β‐ethoxy urethane ethyl methacrylate phenyl)propane (HEPAIEM), 2,2‐bis(4‐β‐ethoxy urethane ethyl methacrylate phenyl)6Fpropane (HEPFAIEM), 2,2‐bis(4‐β‐ethoxy urethane ethyl methacrylate‐3,5‐dibromo phenyl)propane (TBHEPAIEM), and 5‐ tert ‐butyl‐1,3‐bis(4‐ethoxy urethane methacrylate phenyl)benzoylbenzene (tBuHEPBIEM), which can be good candidates for UV‐curable coating applications, were synthesized by reacting isocyanato ethyl methacrylate (IEM) with four different diols. The structures of the monomers thus prepared were characterized by FTIR, mass and 1 H NMR spectroscopies. Introduction of new difunctional cross‐linking agents affected the mechanical and physical properties of UV‐cured films. Addition of 10% cross‐linking agents into the formulations caused an increase both in tensile strength and elongation, when compared with widely used di(ethylene glycol)diacrylate (DEGDA) containing films. Elongation values of TBHEPAIEM containing films were exceptions. Gel contents of the UV‐cured polymeric films were found to be between 88–98%. Thermogravimetric analysis showed that there were not any noticeable changes in thermal oxidative stability of the films compared with DEGDA containing ones. On the other hand, HEPFAIEM and TBHEPAIEM containing films showed increases in char yields due to the presence of F and Br in their structures. Introduction of the new difunctional monomers lowered the water absorption values of the films somewhat proportional to the methyl group content of the x‐linkers.