Premium
A New Strategy for the Synthesis of Polytrithiocarbonates Using a Polymeric Support System
Author(s) -
You YeZi,
Hong ChunYan,
Pan CaiYuan
Publication year - 2002
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/1521-3927(20020901)23:13<776::aid-marc776>3.0.co;2-x
Subject(s) - polymerization , nucleophilic substitution , polymer chemistry , materials science , chemistry , chemical engineering , organic chemistry , polymer , engineering
A new polymerization strategy, consisting of nucleophilic substitution reaction between CS 3 2‐ , immobilized on a polymeric support, and dimethyl α , α ′‐dibromoalkylanedioate in solution, leads to the formation of polytrithiocarbonates. When n = 0, 1 in CH 3 OOCCHBr(CH 2 ) n CHBrCOOCH 3 ( α , α ′‐dibromoalkylanedioate), only five‐ or six‐membered cyclic trithiocarbonates were obtained; n ≥ 2 resulted in the formation of polytrithiocarbonates.