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Preparation of Ethene/Carbon Monoxide Copolymers Using Copper‐Based Catalysts and Their Characterization by Pyrolysis‐Gas Chromatography
Author(s) -
Kiji Jitsuo,
Yamada Akio,
Bertini Fabio,
Audisio Guido
Publication year - 2001
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/1521-3927(20010501)22:8<598::aid-marc598>3.0.co;2-0
Subject(s) - carbon monoxide , copolymer , pyrolysis , gas chromatography , propane , catalysis , copper , polymer chemistry , chemistry , carbon fibers , organic chemistry , materials science , polymer , chromatography , composite material , composite number
Ethene/carbon monoxide copolymers were prepared using the catalyst system Cu(OAc) 2 /dppp (1,3‐bis(diphenylphosphino)propane)/ p ‐toluenesulfonic acid ( p ‐TsOH) or BF 3 ·OEt 2 / p‐ benzoquinone. Pyrolysis‐gas chromatography proves the alternating structure of the copolymers.