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A New Kind of Copolymerization of Styrene and p ‐Quinodimethane Intermediates
Author(s) -
Zhang Ruifeng,
Tang Jiecong,
Zhang Guoqiang,
Shen Jiacong
Publication year - 2001
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/1521-3927(20010301)22:6<383::aid-marc383>3.0.co;2-3
Subject(s) - copolymer , styrene , monomer , polymer chemistry , materials science , derivative (finance) , solubility , chlorine , poly(p phenylene vinylene) , polymerization , chemistry , organic chemistry , polymer , conjugated system , economics , financial economics , composite material , metallurgy
A new kind of copolymerization between styrene and p ‐quinodimethane intermediates was realized by adding styrene to a reaction performed via the typical chlorine precursor route toward the synthesis of poly( p ‐phenylene vinylene) (PPV). The composition and structure of the obtained copolymers can be adjusted by the feed rate of the two monomers. The resulting copolymers show improved solubility and blue‐shifted photoluminescence as compared with the corresponding PPV derivative.