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Versatile and convenient routes to functionalized poly(ferrocenylsilanes)
Author(s) -
Jäkle Frieder,
Wang Zhuo,
Manners Ian
Publication year - 2000
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/1521-3927(20001201)21:18<1291::aid-marc1291>3.0.co;2-0
Subject(s) - monomer , polymer , amine gas treating , polymerization , polymer chemistry , nucleophile , nucleophilic substitution , combinatorial chemistry , ammonium , chemistry , materials science , organic chemistry , catalysis
Abstract Functionalized organometallic polymers are reported. Direct substitution reactions on poly(ferrocenylsilanes) using nucleophiles with protected amines led to amine‐functionalized polymers. The use of protecting group and monomer substitution strategies were found to be compatible with ring‐opening polymerization protocols allowing the synthesis of high polymers with amino, bromo, ester, or quarternary ammonium functionalities.