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Effect of hydrogen bonds on gelation by introduction of carboxyl groups in the free‐radical crosslinking copolymerization of butyl methacrylate with 1,6‐hexanediol dimethacrylate
Author(s) -
Matsumoto Akira,
Ueda Akiyoshi,
Aota Hiroyuki,
Ikeda Junichi
Publication year - 2000
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/1521-3927(20000601)21:10<701::aid-marc701>3.0.co;2-l
Subject(s) - copolymer , polymer chemistry , methacrylate , hydrogen bond , polymer , methyl methacrylate , materials science , 2 hydroxyethyl methacrylate , chemistry , organic chemistry , molecule
The preliminary study of the effect of physical crosslinking on the gelation in monovinyl/divinyl copolymerizations is described. Thus, mono(2‐methacryloyloxyethyl) succinate was added to the crosslinking copolymerization of butyl methacrylate with 1,6‐hexanediol dimethacrylate and the gelation was explored in terms of the effect of hydrogen bonds formed between carboxyl groups introduced into the primary polymer chain.