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Modelling of the Phase Separation Behaviour of Semiflexible Diblock Copolymers
Author(s) -
Friedel Peter,
John Andreas,
Pospiech Doris,
Jehnichen Dieter,
Netz Roland R.
Publication year - 2002
Publication title -
macromolecular theory and simulations
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.37
H-Index - 56
eISSN - 1521-3919
pISSN - 1022-1344
DOI - 10.1002/1521-3919(20020901)11:7<785::aid-mats785>3.0.co;2-e
Subject(s) - olefin fiber , copolymer , polymer , polymer chemistry , raman spectroscopy , methacrylate , materials science , electrolyte , chemical engineering , chemistry , organic chemistry , physics , electrode , optics , engineering
Silver salts are dissolved in poly(butyl methacrylate) to derive polymer electrolytes via coordinative interaction between the silver ion and the carbonyl oxygen atom. The dissolved silver ions react subsequently with propylene to form reversible silver/olefin complexes that can be utilized as olefin carriers for facilitated olefin transport. The complexation behavior and its effects on propylene transport were investigated by means of Raman and FT‐IR spectroscopy, as well as dielectric thermal analysis.