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Self‐organized nanostructures of poly(4‐vinylpyridine), polyaniline and polyamides due to metal complexation
Author(s) -
Valkama Sami,
Hartikainen Juha,
Torkkeli Mika,
Serimaa Ritva,
Ruokolainen Janne,
Rissanen Kari,
ten Brinke Gerrit,
Ikkala Olli
Publication year - 2002
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200208)186:1<87::aid-masy87>3.0.co;2-t
Subject(s) - conjugated system , polyamide , polymer , hydrogen bond , nanostructure , materials science , metal , benzene , polyaniline , polymer chemistry , self assembly , zinc , chemical engineering , nanotechnology , chemistry , molecule , organic chemistry , composite material , polymerization , engineering , metallurgy
Comb‐shaped supramolecules are constructed using flexible polymers and semi‐rigid conjugated undoped or doped conjugated polymers upon complexing Zinc dodecyl benzene sulphonate, Zn(DBS) 2 . Selforganized nanostructures are formed in the bulk due to competing attractive interactions (coordination or water mediated hydrogen bonding) and repulsive polar/nonpolar interactions, showing characteristic long periods of ca. 30 Å.