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Control of the stereochemical structure of silicon‐containing polymers
Author(s) -
Kawakami Yusuke
Publication year - 2001
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200109)174:1<145::aid-masy145>3.0.co;2-s
Subject(s) - organosilicon , siloxane , polymer , monomer , silicon , materials science , polymer chemistry , organic chemistry , chemical engineering , chemistry , engineering
Various optically pure organosilicon compounds were synthesized or separated on HPLC. Stereoregular silicon‐containing polymers, poly(carbosilane)s, poly(carbosiloxane)s and poly(siloxane)s were synthesized from these compounds as monomer. Stereochemistry of the elementary reactions to give stereoregular polymers was elucidated.