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Electrical properties of carbon black‐filled polymer composites
Author(s) -
Zois Haralampos,
Apekis Lazaros,
Omastová Mária
Publication year - 2001
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200106)170:1<249::aid-masy249>3.0.co;2-f
Subject(s) - materials science , composite material , dielectric , carbon black , conductivity , percolation threshold , permittivity , percolation (cognitive psychology) , temperature coefficient , electrical resistivity and conductivity , polypropylene , atmospheric temperature range , percolation theory , thermodynamics , chemistry , natural rubber , electrical engineering , physics , optoelectronics , engineering , neuroscience , biology
This work deals with the dielectric properties of conductive composite materials, which consist of thermoplastic polypropylene (PP) matrix filled with carbon black (CB). The CB concentration was systematically varied in a wide range. Our main interest is focused on the investigation of electrical conductivity mechanism and related percolation phenomena in these materials. To study the electrical and dielectric properties of composites we used broadband ac dielectric relaxation spectroscopy (DRS) techniques in a wide temperature range. By measurements of complex dielectric permittivity, ϵ*, the dependence of ac conductivity, σ ac , and dc conductivity, σ dc , on the frequency, the temperature and the concentration of the conductive filler was investigated. The behavior of this system is described by means of percolation theory. The percolation threshold, P C , value was calculated to be 6.2 wt.% CB. Both, dielectric constant and dc conductivity follow power‐law behavior, yielding values for the critical exponents, which are in good agreement with the theoretical ones. Indications for tunneling effect in the charge carriers transport through the composites are presented. The temperature dependence of dc conductivity gives evidence for the presence of positive temperature coefficient (PTC) effect.