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Interphase structure development in impact modified PP/Mg(OH) 2 composites reactively processed with 1,3‐phenylene dimaleimide
Author(s) -
Liauw Christopher M.,
Khunova Viera,
Lees Graham C.,
Rothon Roger N.
Publication year - 2001
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200106)170:1<205::aid-masy205>3.0.co;2-a
Subject(s) - materials science , phenylene , composite material , toughness , interphase , elastomer , curing (chemistry) , izod impact strength test , magnesium , polymer , ultimate tensile strength , metallurgy , biology , genetics
Interphase modification of impact modified isotactic poly(propene) (IMPP)/magnesium hydroxide (Mg(OH) 2 ) composites, via use of the reactive modifier 1,3 phenylene dimaleimide (BMI) has led to the formation of composites that have strength and toughness more than twice that of the unmodified composite. These significant improvements in properties were found (via response surface analysis, DSC and matrix extraction‐DRIFTS studies) to be due to encapsulation of the filler particles with the elastomeric poly(ethene‐co‐propene) impact modifier phase of the IMPP. Acceptable processing characteristics can be realised together with excellent mechanical properties, via judicious addition of a lubricant (a fatty acid amide/ester blend) to the formulation.