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Tailor‐made polymer supports via metathesis polymerization: concepts and applications
Author(s) -
Buchmeiser Michael R.,
Sinner Frank,
Mupa Mathew
Publication year - 2001
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200101)163:1<25::aid-masy25>3.0.co;2-x
Subject(s) - romp , polymerization , ring opening metathesis polymerisation , materials science , metathesis , surface modification , polymer , polymer chemistry , precipitation polymerization , coating , chemical engineering , polymer science , nanotechnology , radical polymerization , composite material , engineering
Ring opening metathesis polymerization (ROMP) and alkyne polymerization have been applied to the preparation of surface‐functionalized inorganic and organic supports using various coating, grafting, precipitation and bulk‐polymerization techniques. Well‐defined carrier materials in terms of particle diameter, specific surface, pore volume and functionalization have been prepared. The resulting materials have been used for applications in heterogeneous catalysis (e.g. Heck couplings) as well as in bioanalytical (e.g. protein) separations.