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Rheological behaviour of polymer systems in the vicinity of critical regions
Author(s) -
Kerch Garry
Publication year - 2000
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200008)158:1<103::aid-masy103>3.0.co;2-j
Subject(s) - mesoscopic physics , limiting , spinodal , minkowski space , rheology , kinetic energy , mechanics , flow (mathematics) , polymer , thermodynamics , shear flow , physics , shear (geology) , classical mechanics , shear rate , materials science , phase (matter) , condensed matter physics , mathematical physics , quantum mechanics , mechanical engineering , composite material , engineering , nuclear magnetic resonance
Flow induced phase separation in polymer solutions can be considered taking into account that mechanical motion proceeds in Minkowski space‐time. The spinodal temperature shift increasing with increase of the shear rate is interpreted as a result of relativistic effects. Relativistic phenomena can play the important role in processes of flow, especially when velocity of kinetic units on microscopic or mesoscopic level approaches some limiting velocity. The role of the value of limiting velocity in manifestation of relativistic effects was considered and changes of properties of polymers were discussed.