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Electron transfer of conjugated polymeric ferrocenes
Author(s) -
Kurihara Masato,
Kubo Kenya,
Horikoshi Tesuo,
Kurosawa Masaru,
Nankawa Takuya,
Matsuda Takayuki,
Nishihara Hiroshi
Publication year - 2000
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/1521-3900(200007)156:1<21::aid-masy21>3.0.co;2-f
Subject(s) - ferrocene , conjugated system , electrochemistry , electron transfer , polymer , redox , valence (chemistry) , polymer chemistry , materials science , photochemistry , chemistry , organic chemistry , electrode
This paper describes three topics on the π‐conjugated ferrocene oligomers and polymers; the first is the dependence of intervalence‐transfer bands for mixed‐valence oligo(1,1'‐dihexylferrocenylene)s on the oxidation number and the number of ferrocene units, the second is synthesis of azo‐bridged ferrocene oligomers and a polymer and electrochemical and optical analysis of internuclear electronic interactions in their mixed‐valence states and the third is synthesis, redox behaviors and electrodeposition of oligoferrocenylene‐modified gold clusters.