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trans ‐Addition of Two Carbon Substituents across a Benzene Double Bond in [(η 6 ‐Benzene)Mo(CO) 3 ]
Author(s) -
Kündig E. Peter,
Fabritius CharlesH.,
Grossheimann Gabriele,
Robvieux Fabrice,
Romanens Patrick,
Bernardinelli Gérald
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021202)41:23<4577::aid-anie4577>3.0.co;2-4
Subject(s) - benzene , chemistry , carbon fibers , double bond , medicinal chemistry , organic chemistry , materials science , composite number , composite material
No CO insertion occurs in the first Mo(CO) 3 ‐mediated dearomatization reaction sequence (shown). In contrast to the analogous Cr(CO) 3 reaction, the intermediate allyl complex can be isolated.