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Access to C‐15 Macrocyclic Ketones by Iterative Fragmentations of a Tricyclic System
Author(s) -
Fehr Charles,
Galindo José,
Etter Olivier,
Thommen Walter
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021202)41:23<4523::aid-anie4523>3.0.co;2-1
Subject(s) - chemistry , ketone , tricyclic , metathesis , cyclohexanone , yield (engineering) , oxygen atom , stereochemistry , combinatorial chemistry , organic chemistry , molecule , catalysis , materials science , metallurgy , polymerization , polymer
The scent of success! New highly valued unsaturated C‐15‐macrocyclic musks were synthesized in a stereocontrolled manner by two consecutive fragmentations, starting from tricyclic dihydroxy ketone 1 .