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Solvothermal Synthesis, Crystal Structure, Thermal Stability, and Mössbauer Spectroscopic Investigation of the Mixed‐Valent Thioantimonate( III , V ) [Ni(dien) 2 ] 2 Sb 4 S 9
Author(s) -
Stähler Ralph,
Mosel BerndDieter,
Eckert Hellmut,
Bensch Wolfgang
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021202)41:23<4487::aid-anie4487>3.0.co;2-8
Subject(s) - diethylenetriamine , antimony , mössbauer spectroscopy , crystallography , solvothermal synthesis , crystal structure , ion , thermal stability , atom (system on chip) , chemistry , tetrahedron , materials science , stereochemistry , inorganic chemistry , organic chemistry , computer science , embedded system
Antimony in two oxidation states : The mixed‐valent thioantimonate anion [Sb 4 S 9 ] 4− in the compound [Ni(dien) 2 ] 2 Sb 4 S 9 contains Sb V S 4 tetrahedra, which are bound by one terminal S atom to the Sb 3 S 7 backbone of the anion (see figure). dien=diethylenetriamine.