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Towards Main‐Chain‐Polyoxometalate‐Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates
Author(s) -
Xu Lin,
Lu Meng,
Xu Bubin,
Wei Yongge,
Peng Zhonghua,
Powell Douglas R.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021104)41:21<4129::aid-anie4129>3.0.co;2-r
Subject(s) - polyoxometalate , polymer , molybdenum , ion , chain (unit) , materials science , hybrid material , chemistry , polymer chemistry , combinatorial chemistry , chemical engineering , organic chemistry , catalysis , physics , astronomy , engineering
Molybdenum blocks in organic polymers : Bifunctionalized hexamolybdate anions (such as 1 ) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main‐chain‐polyoxometalate‐containing hybrid polymer.