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Naphtho[1,8‐ b , c ]phosphete and 1,2‐Diphosphaacenaphthene from the Reaction of 1,8‐Dilithionaphthalene with RPCl 2
Author(s) -
Mizuta Tsutomu,
Nakazono Tooru,
Miyoshi Katsuhiko
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021018)41:20<3897::aid-anie3897>3.0.co;2-h
Subject(s) - reactivity (psychology) , naphthalene , chemistry , metal , medicinal chemistry , atom (system on chip) , stereochemistry , transition metal , crystallography , organic chemistry , catalysis , medicine , alternative medicine , pathology , computer science , embedded system
Strained rings and metal insertions : The product of the reaction between 1,8‐dilithionaphthalene and RPCl 2 differs depending on the R group on the phosphorus atom. PhPCl 2 gave (PhP) 2 ‐ peri ‐bridged naphthalene, while i Pr 2 NPCl 2 gave the i Pr 2 ‐bridged compound (see scheme). The reactivity of the new compounds with transition‐metal complexes is also discussed.