Premium
Insertion and Cycloaddition Reactivity of a Transition‐Metal N ‐Metalloimine
Author(s) -
Hevia Eva,
Pérez Julio,
Riera Víctor,
Miguel Daniel
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021018)41:20<3858::aid-anie3858>3.0.co;2-j
Subject(s) - cycloaddition , reactivity (psychology) , transition metal , chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology
An enhanced reactivity towards isocyanates was found with compound 1 ([Re] = [Re(CO) 3 (bpy)]) when compared with N ‐silylimines. A crystal structure determination established that 1 is a transition‐metal N ‐metalloimine.