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Novel, Acentric Metal–Organic Coordination Polymers from Hydrothermal Reactions Involving In Situ Ligand Synthesis
Author(s) -
Xiong RenGen,
Xue Xiang,
Zhao Hong,
You XiaoZeng,
Abrahams Brendan F.,
Xue Ziling
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021018)41:20<3800::aid-anie3800>3.0.co;2-3
Subject(s) - acentric factor , ligand (biochemistry) , in situ , metal , hydrothermal reaction , hydrothermal synthesis , chemistry , polymer , hydrothermal circulation , coordination polymer , polymer chemistry , materials science , crystallography , chemical engineering , organic chemistry , receptor , biochemistry , engineering
The pyridyltetrazolate ligand formed in situ from NaN 3 and 3‐cyanopyridine in the presence of ZnCl 2 or CdCl 2 in water affords acentric ( 1 ) or chiral ( 2 ) coordination polymers, respectively. The corresponding reaction of ZnCl 2 with 4‐cyanopyridine gives acentric 3 (not shown). Compounds 1 – 3 are second harmonic generation active.