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Tuning Electronic Behavior of Carbonyl Metal Clusters by Substitution of Interstitial and Capping Atoms
Author(s) -
Collini Davide,
Femoni Cristina,
Iapalucci Maria Carmela,
Longoni Giuliano,
Svensson Per H.,
Zanello Piero
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021004)41:19<3685::aid-anie3685>3.0.co;2-7
Subject(s) - isostructural , substitution (logic) , chemistry , crystallography , metal , cluster (spacecraft) , electronic structure , transition metal , computational chemistry , crystal structure , organic chemistry , catalysis , computer science , programming language
The progressive replacement of Rh with Ni modulates the electronic as well as chemical properties of body‐centered [Rh 14− x Ni x (CO) 9 ( μ ‐CO) 16 ] n − clusters ( x =0, n =4; x =1, n =5 (shown here); x =2, n =4; x =5, n =2, 3) and prompts multivalence. The complexes obtained are isostructural, but not isoelectronic.