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(C 2 H 10 N 2 )[Cr(HPO 3 )F 3 ]: The First Organically Templated Fluorochromium( III ) Phosphite
Author(s) -
Fernández Sergio,
Mesa José L.,
Pizarro José L.,
Lezama Luis,
Arriortua María I.,
Rojo Teófilo
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021004)41:19<3683::aid-anie3683>3.0.co;2-j
Subject(s) - tetrahedron , octahedron , antiferromagnetism , hydrothermal circulation , crystallography , hydrothermal synthesis , chemistry , crystal structure , materials science , inorganic chemistry , chemical engineering , physics , engineering , condensed matter physics
Mild hydrothermal conditions can be used to synthesize the first inorganic–organic hybrid fluorochromium( III ) phosphite. The crystal structure (see unit cell) shows that the material consists of double chains of alternating CrO 3 F 3 octahedra and HPO 3 tetrahedra. Furthermore, the magnetic behavior indicates the existence of antiferromagnetic interactions.