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Single‐Step Assembly of a C 2 ‐Symmetrical Palladium( IV ) Spirocyclic Complex
Author(s) -
Yamamoto Yoshihiko,
Ohno Takuya,
Itoh Kenji
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021004)41:19<3662::aid-anie3662>3.0.co;2-t
Subject(s) - palladium , norbornene , chemistry , benzoquinone , chelation , crystallography , ligand (biochemistry) , ether , stereochemistry , organic chemistry , polymerization , receptor , catalysis , polymer , biochemistry
A pair of seven‐membered chelate rings are found in the palladium( IV ) complex assembled in only a single step from commercially available [Pd 2 (dba) 3 ], tetrachloro‐1,2‐benzoquinone, and norbornene. The structure consists of a C 2 ‐symmetrical palladaspirocycle framework and an ether ligand, as confirmed by X‐ray analysis of the thf complex (see picture).