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Self‐Assembly Using Organometalloligands as Spacers in the Controlled Formation of Isomeric 1D and 2D Supramolecular Quinonoid Networks
Author(s) -
Oh Moonhyun,
Carpenter Gene B.,
Sweigart Dwight A.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021004)41:19<3650::aid-anie3650>3.0.co;2-6
Subject(s) - supramolecular chemistry , self assembly , ion , metal ions in aqueous solution , chemistry , metal , benzoquinone , crystallography , crystal structure , organic chemistry
The concentration of metal ions influences the structural characteristics of self‐assembled coordination polymers constructed from Mn 2+ ions and [( η 4 ‐benzoquinone)Mn(CO) 3 ] − ions. At very low metal‐ion concentrations, 1D “string” formations are obtained (see picture), while at higher concentrations, 2D “grid” networks are formed.